Structural ordering in glass forming tellurium-germanium melts

The character of reorganization of the short-range order and the scale structure during the ordering of glass forming melts is elaborated based on the results of diffraction and microscopic investigations of the ordered and glassy alloys in tellurium-germanium systems. For this purpose cooling curves reflecting the formation processes of structural levels in real time are analyzed and the effective activation energies are estimated.     

The Reclaim Screw in Mammoth Silos Operating on a Free Surface: Comparison Between Horizontal and Inclined Operation on Free Flowing Bulk Solids

Although the screw conveyor, operating on a free surface, has been used for years as reclaim and storage equipment in mammoth silos, there is no documented knowledge about its spill characteristics. Research at Delft University of Technology together with ESI Eurosilo B.V. on the inclined use of the reclaim screw to achieve homogenization in mammoth silos made this lack of knowledge apparent. This paper presents the results of experiments to gain insight into the spill during reclaiming. Experiments were conducted reclaiming a horizontal surface and up‐ and downwards along an inclined surface, using a free‐flowing bulk material. A relationship was found between the theoretical and effective fill ratio. This relationship shows a certain maximum effective fill ratio and a dependence on the reclaim‐depth. As expected, the effective fill ratio drops quickly when reclaiming upwards, mostly due to flow‐ and throwback: the fill is spilled behind the screw blades and over the axis. Unexpectedly, the effective fill ratio also decreases when reclaiming downwards due to a shift of material towards the non‐reclaiming side where it is left behind forming ridges on the surface. It is expected that all three mechanisms will cause less spill when reclaiming a cohesive material. The experiments provide the desired insight into spill mechanisms during reclaiming. Indeed, the inclined use of the reclaim screw to achieve homogenization is thought feasible when reclaiming downwards.     

Use of computational fluid dynamics simulations for design of a pretreatment screw conveyor reactor

Computational fluid dynamics simulations were employed to compare performance of various designs of a pretreatment screw conveyor reactor. The reactor consisted of a vertical screw used to create cross flow between the upward conveying solids and the downward flow of acid. Simulations were performed with the original screw design and a modified design in which the upper flights of the screw were removed. Results of the simulations show visually that the modified design provided favorable plug flow behavior within the reactor. Pressure drop across the length of the reactor without the upper screws in place was predicted by the simulations to be 5 vs 40 kPa for the original design.     

Rheological and mechanical properties of nylon 6 nanocomposites submitted to reprocessing with single and twin screw extruders

The effect of multiple extrusions on nanostructure and properties of nylon 6 nanocomposites was investigated. Nanocomposites at different silicate loadings were produced by melt compounding and submitted to further reprocessing by using single and twin screw extruders. Rheological, morphological and mechanical analyses were carried out on as-produced and reprocessed samples in order to explore the influence of the number and the type of extrusion cycles on silicate nanodispersion.Rheological measurements, correlated to TEM analyses, were used to probe the nanoscale arrangement developed with the reprocessing as well as the thermo-mechanical degradation involving both the neat matrix and the organoclay. The results have shown that the reprocessing by single screw extruder can modify the initial morphology since the re-agglomeration of the silicate layers can occur. On the other hand, a better nanodispersion was observed in the hybrids reprocessed by twin screw extruder. This was attributed to the additional mechanical stresses able to realizing a dispersive mixing that contributes to avoid re-agglomeration phenomena. The high shear stresses produced with twin screw geometry determined also a significant degradation of neat matrix, principally based on chain scission mechanism.A strong correlation between the rheological behaviour and mechanical properties was observed and all as-produced and reprocessed hybrids showed a substantial enhancement in tensile modulus with the adding of silicate. However, the entity of performance enhancements displayed by the reprocessed hybrids was found to be highly dependent on the degradation of both organoclay and polymer matrix as well as the silicate amount, the number and the type reprocessing.     

振动钻削微小孔中钻头寿命与振动参数的二次回归试验研究

本文采用正交组合设计的试验方法，对振动钻削微小孔加工中钻头寿命与轴向振动参数之间的非线性关系进行了二次回归试验，得到了最优回归方程。用回归方程给出的最佳振动参数钻孔，钻头寿命提高了９６．３％     

The interaction between a screw dislocation and an interfacial cruciform crack and collinear linear cracks

The interaction between a screw dislocation and an interfacial cruciform crack and collinear linear cracks under loads at infinity was investigated. General solutions of complex potentials to this problem were derived by using complex potential theory. As illustrative examples, the closed form solution for a screw dislocation interacting with an interfacial cruciform crack and a linear crack is obtained. The stress intensity factor and critical stress intensity factor for dislocation emission are also calculated. The results show that the shielding effect increases with the increase of the shear modulus and the distance between the two cracks, but it decreases with the increase of dislocation azimuth and the distance between the dislocation and the cruciform crack tip. The critical loads at infinity for dislocation emission increase with the increment of the emission angle, the distance the two cracks and the vertical length of the cruciform crack.     

Comparative Study on Heat Transfer Enhancement of Low Volume Concentration of Al2o3–Water and Carbon Nano-Tube–Water Nano-Fluids in Transition Regime Using Helical Screw Tape Inserts

This study reports the comparison of heat transfer and friction factor characteristics of helical screw inserts in Al₂O₃–water and carbon nano-tube–water nano-fluids through a straight pipe in transition regime with constant heat flux boundary condition. Experiments were carried out by using 0.15% volume concentration of Al₂O₃–water and carbon nano-tube–water nano-fluid with helical tape inserts of twist ratio, TR = 1.5, 2.5, and 3. The thermal performance of helical screw tape inserts with the carbon nano-tube–water nano-fluid is found -to be higher when compared to the Al₂O₃–water nano-fluid. In addition, the maximum enhancement in heat transfer was obtained for the carbon nano-tube–water nano-fluid with helical tape inserts of twist ratio 1.5. The increase in pressure drop of the Al₂O₃–water nano-fluid with helical screw tape inserts is found to be higher compared to the carbon nano-tube–water nano-fluid helical screw tape inserts at lower value of twist ratio.     

A SCREW DISLOCATION IN A THREE-PHASE COMPOSITE CYLINDER MODEL WITH INTERFACIAL RIGID LINES

The problem of the elastic interaction between a screw dislocation and a three-phase circular inclusion with interracial rigid lines （anti-cracks） is investigated. An efficient and concise method for the complex multiply connected region is developed, with which explicit series form solutions of the complex potentials in the matrix, and the interphase layer and inclusion regions are derived. Based on the complex potentials, the image force on the screw dislocation is then calculated by using the Peach-Koehler formula. The equilibrium position of the dislocation is discussed in detail for various rigid line geometries, interphase layer thicknesses and material property combinations. The main results show that the interracial rigid lines exert a significant perturbation effect on the motion of the screw dislocation near the circular inclusion surrounded by an interphase layer.     

Polystyrene prepared by reactive extrusion: kinetics and effect of processing parameters

The conversion and residence time were investigated during the bulk polymerization of styrene in a twin screw extruder. It was found that polymerization mainly occurred in the zone between 400 and 1000 mm along the screw axis in the extruder, corresponding to the residence time of the reactants ranging from 1 to 4 min in the extruder. Furthermore, the processing conditions (feed rate, screw rotation rate) and average molecular weight of the polymer have a great effect on the residence time. Based on dimensionless analysis, a model of the residence time has been built‐up, which has been confirmed by the results of realistic measurements. A kinetic model of the polymerization has also been established under the assumption that the screw extruder can be regarded as an ideal plug flow reactor. Copyright © 2004 John Wiley & Sons, Ltd.     

Large‐scale extrusion processing and characterization of hybrid nylon‐6/SiO2 nanocomposites

Solution impregnations, pulltrusion and film stacking are widely used methods to prepare thermoplastic composite materials. Extruders are used to melt the polymer and to incorporate fibers into the polymer in order to modify physical properties. In this article, the compounding of colloidal silica nanoparticles filled polyamide‐6 (PA‐6) is achieved using a twin‐screw extruder, which has a significant market share due to its low cost and easy maintenance. The experiments were performed at 250 rpm and the bulk throughput was 6 kg h^?1 with a pump pressure of 30 bars. The composites were characterized with nuclear magnetic resonance (NMR), wide angle X‐ray diffraction (WAXD), differential scanning calorimetry (DSC) and transmission electron microscopy (TEM). As determined by WAXD, the PA‐6 showed higher amounts of γ‐phase when compared to other synthesis methods such as in situ polymerization. TEM pictures showed that the silica particles aggregated nevertheless, upon addition of 14% (w/w) silica the E‐modulus increased from 2.7 to 3.9 GPa indicating that an effective mechanical coupling with the polymer was achieved. The behavior, illustrated with dynamic mechanical analysis (DMA) curves, indicated that in general when a filled system is compared to unfilled material, the values of the moduli (E′ and E″) increased and tan δ decreased. Determination of molecular mass distribution of the samples by means of size exclusion chromatography (SEC) coupled to a refractive index (RI), viscosity (DV) and light scattering (LS) detector revealed that the addition of silica did not decrease the average molecular weight of the polymer matrix, which is of importance for composite applications. Copyright © 2004 John Wiley & Sons, Ltd.